Sulphuric acid is oxidising when concentrated but is reducing at low and 'intermediate' concentrations.
The response of most stainless steel types is that in general they are resistant at either low or high concentrations, but are attacked at intermediate concentrations. Commercially concentrated acid is around 96 wt % (sg = 1.84).
The improvement in corrosion resistance moving from stainless steel 304 /1.4301 to 316 / 1.4401 is due to the addition of molybdenum. Further additions of moybdenum and copper in the 1.4539 904L grade extend the corrosion resistance in these reducing acid conditions. The molybdenum in types 316 stainless steel and grade 1.4539 also helps improve resistance to chloride attack, when present as impurities in the acid.


